Aliphatic and Related Natural Product Chemistry Volume 2 by Frank D Gunstone

By Frank D Gunstone

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Bohlmann and U. Fritz, Phytochemistry, 1979,18,1888. Gaughan and C. D. Poulter, J. Org. , 1979,44,2441. P. Vig, S. D. Sharma, S. D. Kumar, and V. K. Handa, Indian J. , Sect. B , 1978,16,740. Aliphatic and Related Natural Product Chemistry 24 4 2,6-Dimethyloctane Group Ocimenes. % A Japanese group has reported2’ syntheses of ocimenol (27) and of dihydroallo-ocimenol (28). New routes to dihydrotagetone (29)30and t o tagetone (30) [ ( E ) l ( Z )ratio 55 : 451 (see Scheme 5)31 have also been revealed.

Org. , 1978,14, 1851 (Chem. A b s . , 1978,90, 23 205). l Z o N. Ya. Grigor'eva, I. M. Avrutov, A. V. Semenovskii, V. N. Odinokov, V. R. Akhunova, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. , 1979, 382 (Chem. , 1 9 7 9 , 9 1 , 7 4 720). l Z 1 E. Lemmich, Phytochemistry, 1979,18, 1195. r. '" Electrochemical epoxidation of ( 168) affordslM the o-epoxide with high specificity. A new synthesis of geranylfarnesol (169) has been r e ~ 0 r t e d . I ~ ~ 7 Squalene Group Squalene (170) has been detected in extracts of Bryocladia c ~ s p i d a t a .

28 The C26-C35and C39 compounds were synthesized for reference purposes. " J. Albraiges, J. Borbon, and P. , 1978, 595. Y. Fujita, T. Onishi, and T. Nishida, Synthesis, 1978,934. Fujita, S. Amiya, T. Onishi, and T. Nishida, Bull. Chem. Jpn, 1979,52,1983. 12' 129 3 Insect Pheromones and Related Behaviour-modifying Chemicals R. B A K E R & J. W. S. B R A D S H A W 1 Introduction Since the previous Specialist Periodical Report on this subject,’ the literature on naturally occurring chemicals which modify insect behaviour has increased in volume.

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